Learn about USING the past perfect here.
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The positive - make it with 'had' + the past participle (usually made by adding 'ed' to the infinitive, but a few verbs have irregular past participles):
(Also, here's some help if you are not sure how to pronounce '-ed' at the end of a verb).
- I had been (I'd been)
 - You had gone (you'd gone)
 - She had met (she'd met)
 - He had played (he'd played)
 - It had rained (it'd rained)
 - We had bought (we'd bought)
 - They had studied (they'd studied)
 
The short form for 'had' is 'd. 
(Be careful not to confuse it with 'would'. Would is followed by the infinitive - 'I'd go', whereas had is followed by the past participle - 'I'd gone').
For the negative just add 'not':
- I had not been (I hadn't been)
 - You had not gone (you hadn't gone)
 - She had not met (she hadn't met)
 - He had not played (he hadn't played)
 - It had not rained (it hadn't rained)
 - We had not bought (we hadn't bought)
 - They had not studied (they hadn't studied)
 
Here's a exercise about the positive and negative forms.
And to make a 'yes / no' question put 'had' before the subject:
- Had I come?
 - Had you eaten?
 - Had she gone?
 - Had it rained?
 - Had he studied?
 - Had we met?
 - Had they left?
 
For 'wh' questions put the question word at the beginning:
- When had I come?
 - Why had you eaten?
 - Where had she gone?
 - When had it rained?
 - Why had he studied?
 - How had we met?
 - When had they left?
 
Finally here's an exercise about past perfect questions.
Learn about USING the past perfect here.
Click here for our complete programme to perfect your English grammar.